Clad vanadium pentoxide doped with silver and antistat layers containing the same

ABSTRACT

Clad fibrous vanadium pentoxide, antistat layers containing clad fibrous vanadium pentoxide and imaging elements containing such antistat layers.

This is a continuation of application Ser. No. 129,839, filed 30 Sep. 1993, now U.S. Pat. No. 5,455,153.

FIELD OF THE INVENTION

This invention relates to clad vanadium pentoxide materials, to antistat layers containing such materials and to photographic elements containing an antistat layer containing the vanadium pentoxide clad materials.

DESCRIPTION OF RELATED ART

U.S. Pat. No. 4,203,769 teaches a method of preparation for vanadium pentoxide and the use of such materials in antistat layers of various types, primarily for use in photographic elements.

U.S. Pat. No. 5,006,451 is an improvement over the previously mentioned patent in that it provides for barrier layers over the vanadium pentoxide containing layer in order to impart a high level of permanent antistatic protection to the vanadium pentoxide layer. This barrier layer, for example, prevents the diffusion of the vanadium pentoxide from the photographic element during processing thereof. This diffusion represents a serious problem in that once the vanadium pentoxide is removed the antistatic action of the layer is no longer available.

There is a need in the industry to provide vanadium pentoxide, fibrous structures and layers that are not susceptible to the diffusing out of the vanadium pentoxide and the disadvantages associated therewith including the loss of antistat properties. It is also a need to provide user-friendly methods and techniques for protecting vanadium pentoxide containing articles from this disadvantage. Further, there is a need to provide protection for vanadium pentoxide containing articles of manufacture which is both transparent and colorless and not affected by ranges in humidity conditions.

SUMMARY OF THE INVENTION

This invention provides for the protection of vanadium pentoxide containing articles by providing a cladding to the articles, the cladding being the oxidation product of an oxidatively polymerizable compound. The vanadium pentoxide articles can be formed of fibrous vanadium pentoxide or can be made up of layers of particles or fibrous vanadium pentoxide prior to the cladding operation. By the term "clad" or "cladding" is meant that the fibers or articles of vanadium pentoxide are coated with a continuous film of the polymer resulting from the oxidation of an oxidatively polymerizable compound or that a discontinuous film is formed on the surface of the vanadium pentoxide material.

DESCRIPTION OF THE PREFERRED EMBODIMENTS

The term "vanadium pentoxide" as used herein includes both vanadium pentoxide (V₂ O₅) per se, as well as doped vanadium pentoxide, the doping being other elements such as silver, lithium fluoride, calcium oxide, zinc oxide, silica, lithium carbonate, boron oxide, lithium tetraborate and the like.

While the invention is applicable to the cladding of all forms of vanadium pentoxide, including fibrous vanadium pentoxide and layers formed of particles or fibrous vanadium pentoxide for the purpose of simplicity in explanation, throughout the remainder of this specification, layers formed from vanadium pentoxide as described in U.S. Pat. Nos. 4,203,769 and 5,006,451 will be spoken of for the purpose of simplicity. Both of these patents are incorporated herein in their entirety.

Also, while the invention is applicable to the use of vanadium pentoxide, generally in any antistatic application, it is particularly applicable as an antistatic layer of an imaging element and in the remainder of this specification will be referred to as an antistatic layer for this purpose. By "imaging element" is meant any of the well known types such as, silver halide photographic elements, thermal imaging elements, electrophotographic elements and the like.

Useful photographic elements include those prepared on any of a wide variety of photographic supports. Typical photographic supports include polymeric film, such as, for example, cellulose nitrate and cellulose esters such as cellulose triacetate and diacetate, polystyrene, polyamides, homo- and co-polymers of vinyl chloride, poly(vinylacetal), polycarbonate, homo- and co-polymers of olefin, such as, polyethylene, polypropylene and the like, polyesters of dibasic aromatic carboxylic acids with glycols, such as, poly(ethylene terephthalate), poly(ethylene naphthalate) and the like. Photographic elements which employ paper supports coated with baryta and/or polyolefins, particularly polymers of alpha-olefins containing 2 to 10 carbon atoms in the repeating unit, such as polyethylene, polypropylene, co-polymers of ethylene and propylene and the like are also contemplated.

The polyester film supports which can be advantageously employed in this invention are well known and widely used materials. Such film supports are typically prepared from high molecular weight polyesters derived by condensing a dihydric alcohol with a dibasic saturated fatty carboxylic acid or derivatives thereof. Suitable dihydric alcohols for use in preparing polyesters are well known in the art and include any glycol wherein the hydroxyl groups are on the terminal carbon atom and contain from 2 to 12 carbon atoms such as, for example, ethylene glycol, propylene glycol, trimethylene glycol, hexamethylene glycol, decamethylene glycol, dodecamethylene glycol, and 1,4-cyclohexane dimethanol. Dibasic acids that can be employed in preparing polyesters are well known in the art and include those dibasic acids containing from 2 to 16 carbon atoms. Specific examples of suitable dibasic acids include adipic acid, sebacic acid, isophthalic acid, terephthalic acid, 1,6-naphthalene dicarboxyolic and the like. The alkyl esters of the above-enumerated acids can also be employed satisfactorily. Other suitable dihydric alcohols and dibasic acids that can be employed in preparing polyesters from which sheeting can be prepared are described in J. W. Wellman, U.S. Pat. No. 2,720,503, issued Oct. 11, 1955.

Specific preferred examples of polyester resins which, in the form of sheeting, can be used in this invention are poly(ethylene terephthalate), poly(cyclohexane 1,4-dimethylene terephthalate) and polyethylene naphthalate.

In carrying out the present invention, it is generally advantageous to employ a polymeric subbing layer between a polyester film support and the antistatic layer. Polymeric subbing layers used to promote the adhesion of coating compositions to polyester film supports are very well known in the photographic art. Useful compositions for this purpose include interpolymers of vinylidene chloride such as vinylidene chloride/acrylonitrile/acrylic acid terpolymers or vinylidene chloride/methyl acrylate/itaconic acid terpolymers. Such compositions are described in numerous patents such as for example, U.S. Pat. Nos. 2,627,088, 2,698,235, 2,698,240, 2,943,937, 3,143,421, 3,201,249, 3,271,178, 3,443,950 and 3,501,301. The polymeric subbing layer is typically overcoated with a second subbing layer comprised of gelatin which is typically referred to in the art as a "gel sub".

As discussed hereinabove, the antistatic layer of this invention comprises vanadium pentoxide as the antistatic agent. The advantageous properties of vanadium pentoxide are described in detail in Guestaux, U.S. Pat. No. 4,203,769 and Anderson et al. U.S. Pat. No. 5,006,451. The antistatic layer is typically prepared by the coating of a colloidal solution of vanadium pentoxide. Preferably, the vanadium pentoxide is doped with silver. To achieve improved bonding, a polymeric binder, such as a latex of a terpolymer of acrylonitrile, vinylidene chloride and acrylic acid, can be added to the colloidal solution of vanadium pentoxide. In addition to the polymeric binder and the vanadium pentoxide, the coating composition employed to form the antistatic layer can contain a wetting agent to promote coatability.

The protective cladding layer in accordance with this invention comprises a layer which serves to clad the vanadium pentoxide or doped vanadium pentoxide fibers as a protective layer without the necessity for forming a continuous layer. The protective cladding layer is formed by applying an overcoat layer of an oxidatively polymerizable compound, which compound may be applied neat to the vanadium pentoxide or in the form of an aqueous solution, a solvent solution or as a vapor. Since vanadium pentoxide is a particularly good oxidant for the oxidatively polymerizable monomer, the polymer forms in situ to thus prepare the protective cladding layer.

While any suitable solvent may be used in the preparation of the solvent solution containing the oxidatively polymerizable monomer in accordance with this invention, such as, for example, benzene, toluene, hydrocarbons such as hexane, octane, and the like, chlorinated hydrocarbons including methylene chloride dichlorethane and the like, the preferred methods of preparing the protective polymer layer are by either aqueous solutions or by employing the oxidatively polymerizable monomer in the vapor phase. When employing an aqueous solution, it is preferred to also employ in the aqueous solution a suitable surfactant including non-ionic surfactants such as, for example, P-nonyl phenoxy polyglycidol available commercially as Olin 10 G, ##STR1##

Polyoxyethylene sorbitan tristearic ester, n=30, ##STR2## and the like.

When the oxidatively polymerizable monomer is applied in the vapor phase, it is preferred first to condition the vanadium pentoxide fibers by subjecting them initially to high relative humidity conditions for a suitable period of time. In each case, upon application of the oxidatively polymerizable monomer, the coatings are subsequently dried to produce the final fibrous vanadium pentoxide clad materials.

Because the oxidatively polymerizable monomers are generally conductive by nature, the combination of the vanadium pentoxide with the resulting polymer layers provide improved conductivity and, as a result, improved antistat layers.

Oxidatively polymerized monomers, in accordance with this invention, include anilines, pyrroles, thiophenes, furans, selenophenes and tellurophenes.

Aniline compounds suitable for use in accordance with this invention are represented by the following general formula: ##STR3##

Here, R₁ and R₂ represent hydrogen, halogen (e.g., fluorine, chlorine, bromine), alkyl, aryl, hydroxyl, alkoxy, aryloxy, amino, alkylamino (may be a condensed ring), nitro, cyano, ##STR4## heterocyclic (e.g. triazoles, thiazoles, benzthiazoles, furans, pyridines, quinaldines, benzoxazoles, oxazoles, pyrimidines, imidazoles). R³ and R⁴ represent hydrogen, alkyl or aryl. R⁵ represents alkyl or aryl. R⁶ and R⁷ can be the same or different and represent hydrogen, alkyl or aryl.

Furthermore, the alkyl groups, aryl, alkoxy, aryloxy and alkylamino of R¹ and R² above can be substituted. Moreover, the above alkyl and aryl of R³, R⁴, R⁵, R⁶ and R⁷ can also be substituted. As examples of these substituents, alkoxy (e.g. methoxy, ethoxy), aryloxy (e.g. phenyloxy), alkoxycarbonyl (e.g. methoxycarbonyl), acylamino (e.g. acetylamino), carbamoyl, alkylcarbamoyl (e.g. methylcarbamoyl, ethylcarbamoyl), dialkylcarbamoyl (e.g. dimethylcarbamoyl), arylcarbamoyl (e.g. phenylcarbamoyl), alkylsulfonyl (e.g. methylsulfonyl), arylsulfonyl (e.g. phenylsulfonyl), alkylsulfonamide (e.g. methanesulfonamide), arylsulfonamide groups (e.g. phenylsulfonamide), sulfamoyl, alkylsulfamoyl (e.g. ethylsulfamoyl), dialkylsulfamoyl (e.g. dimethylsulfamoyl), alkylthio (e.g. methylthio), arylthio (e.g. phenylthio), amino, alkylamino, cyano, nitro and halogen (e.g. fluorine, chlorine, bromine) can be cited. When there are two or more of these substituents, they can be the same or different.

Specific eximples of suitable aniline compounds include aniline, N-methylaniline, N-ethylaniline, N-phenylaniline, methylaniline, ethylaniline, n-propylaniline, iso-propylaniline, n-butylaniline, methoxyaniline, ethoxyaniline, n-propoxyaniline, phenylaniline, toluylaniline, naphthylaniline, phenoxyaniline, methylphenoxyaniline, naphthoxyaniline, aminoaniline, phenylaminoaniline, methylphenylaminoaniline, dimethylaminoaniline, diethylaminoaniline, diphenylaminoaniline, phenylnaphthylaminoaniline and the like.

Pyrrole compounds suitable for use in accordance with this invention are those represented by the following formula: ##STR5## where R¹ and R² represent independently hydrogen, halogen, alkyl, aryl, hydroxyl, alkoxy, aryloxy, amino, alkylamino (including a contracted ring radical), nitro, cyano, ##STR6## or may be joined together to form a heterocyclic ring; R³ represents hydrogen, alkyl, or aryl; R⁴ represents an allkyl or aryl; R⁵ and R⁶ may be identical or different and they represent hydrogen, alkyl, or aryl.

In addition, the alkyl, aryl, alkoxy, aryloxy, and alkylamino represented by said R¹ and R² may be substituted. Besides, the alkyl or aryl represented by said R², R⁴, R⁵ and R⁶ may also be substituted. Examples of the substituents include alkoxy (such as methoxy, ethoxy), aryloxy (such as phenyloxy), alkoxycarbonyl (such as methoxycarbonyl), acylamino (such as acetylamino), carbamoyl (such as methylcarbamoyl, ethylcarbamoyl), dialkylcarbamoyl (such as dimethylcarbamoyl), arylcarbamoyl (such as phenylcarbamoyl), alkylsulfonyl (such as methylsulfonyl), arylsulfonyl (such as phenylsulfonyl), alkylsulfonamide (such as methanesulfonamodo), arylsulfonamido (such as phenylsulfonamido), sulfamoyl or alkylsulfamoyl (such as ethylsulfamoyl), dialkylsulfamoyl (such as dimethylsulfamoyl), alkylthio (such as methylthio), arylthio (such as phenylthio), amino, alkylamino, cyano, nitro, halogen (such as fluorine, chlorine, bromine) and the like. It is possible to use two or more of the aforementioned substituents.

Specific examples of pyrroles include: ##STR7##

Other heterocyclic compounds for use in preparing polymers in accordance with this invention include those represented by the general formula: ##STR8## where R¹, R₂, R³ and R₄ independently represent hydrogen, halogen (e.g. fluorine, chlorine, bromine), alkyl, aryl, hydroxyl, alkoxy, aryloxy, amino, alkylamino, nitro, cyano, --NHCOR5, --NHSO₂ R⁵, --SOR⁵, --SO₂ R⁵, --SO₂ N(R⁶)(R⁷), --COR⁵, --CON(R⁶)(R⁷), --COOH, --COOR⁵, --SO₃ H, --SH, or a heterocyclic group (e.g. triazole, thiazole, benzothiazole, furan, pyridine, quinaldine, benzoxazole, pyrimidine, oxazole, imidazole); R⁵ represents alkyl or aryl; R⁶ and R⁷ may be same or different and each represents hydrogen, alkyl or aryl; X represents O, S, Te or Se; when X is not S, R¹ and R², or R¹ and R³ and/or R² and R⁴ each may form a ring; when X is S, R¹ and R³ and/or R² and R⁴ each may form a ring; and in such a case, the ring to be formed may contain one or more hetero atoms.

The alkyl, aryl, alkoxy, aryloxy or alkylamino group for the above-mentioned groups R¹, R², R³ and R⁴ may optionally be substituted. The alkyl or aryl group for the above-mentioned groups R⁵, R⁶ and R⁷ may also be optionally substituted. As examples of substituents for the groups, there are mentioned alkoxy (e.g. methoxy, ethoxy), aryloxy (e.g. phenyloxy), alkoxycarbonyl (e.g. methoxycarbonyl), acylamino (e.g. acetylamino), carbamoyl, alkylcarbamoyl (e.g. methylcarbamoyl, ethylcarbamoyl), dialkylcarbamoyl (e.g. dimethylcarbamoyl), arylcarbamoyl (e.g. phenylcarbamoyl), alkylsulfonyl (e.g. methylsulfonyl, arylsulfonyl (e.g. phenylsulfonyl), alkylsulfonamido (e.g. methanesulfonamido), arylsulfonamido (e.g. phenylsulfonamido), sulfamoyl, alkylsulfamoyl (e.g. ethylsulfamoyl), dialkylsulfamoyl (e.g. dimethylsulfamoyl), alkyithio (e.g. methylthio, arylthio (e.g. phenylthio), amino, alkylamino, cyano, nitro, and halogen (e.g. fluorine, chlorine, bromine) and the like. Where the group has two or more of such substituents, they may be the same or different from each other.

Specific examples of heterocycles of the above formula include: ##STR9##

Selenium and tellurium can replace the oxygen and sulfur atoms of the above heterocyclic compounds as examples of selenophenes and tellurophenes.

The antistatic layer comprising vanadium pentoxide and the overlying cladding layer can be coated at any suitable coverage, with the optimum coverage of each depending on the particular photographic product involved. Typically, the antistatic layer is coated at a dry weight coverage of from about 1 (0.09 mg/ft²) to about 25 (2.3 mg/ft²) milligrams per square meter. mg/ft² is converted to mg/m² by multiplying by 10.76. Typically, the cladding layer is coated at a dry weight coverage of from about 10 to about 1000 milligrams per square meter.

Emulsions containing various types of silver salts can be used to form the silver halide layers, such as silver bromide, silver iodide, silver chloride or mixed silver halides such as silver chlorobromide, silver bromoiodide or silver chloroiodide. Typically silver halide emulsions are taught in patents listed in Product Licensing Index, Vol. 92, December 1971, publication 9232, at page 107.

The silver halide emulsions used in combination with the conductive support of this invention can also contain other photographic compounds such as those taught in Product Licensing Index, op. cit., pages 107-110. The photographic compounds include development modifiers that function as speed increasing compounds, such as polyalkylene glycols, and others; anti-foggants and stabilizers such as thiazolium salts and others; hardeners, such as aldehydes, and others; vehicles, particularly hydrophilic vehicles, such as gelatin, and others; brighteners, such as stilbenes, and others; spectral sensitizers, such as merocyanines, and others; absorbing and filter dyes, such as those described in Sawdey et al. U.S. Pat. No. 2,739,971, issued Mar. 27, 1956, and others; color materials for color photography film elements, such as color-forming couplers in U.S. Pat. No. 2,376,679 issued May 22, 1945; and coating aids, such as alkyl aryl sulfonates, and others. The photographic compounds include, also, mixtures of coating aids such as those disclosed in U.S. Pat. No. 3,775,126, issued Nov. 27, 1973, which can be used in simultaneous coating operations to coat hydrophilic colloid layers on the subbing layers of elements intended for color photography, for example, layers of silver halide emulsions containing color-forming couplers or emulsions to be developed in solutions containing couplers or other color-generating materials as disclosed above.

The invention will be further illustrated by the following examples in which parts and percentages are by weight unless otherwise specified.

EXAMPLES 1-9 Preparation of Antistat Layers

An aqueous antistatic formulation comprised of 0.057 percent silver-doped vanadium pentoxide and 0.02 percent of a nonionic surfactant was coated with a doctor blade onto a polyethylene terephthalate film support which had been subbed with a terpolymer latex of acrylonitrile, vinylidene chloride and acrylic acid. The coating was air dried at 90° C. to form an antistatic layer with a dry weight of approximately 4 milligrams per square foot and a measured conductivity of 1×10⁷ ohms/sq. An aqueous formulation comprised of 1 weight percent aniline and 0.02 weight percent nonionic surfactant was coated onto this film using a doctor blade. The coating was dried at 90° C. for 5 minutes and at 125° C. for 1 minute to form an antistatic layer with a measured conductivity of 1×10⁶ ohms/sq. This coating was exposed to 0.05M aqueous NaOH for 1 minute to give an antistatic layer with a measured conductivity of 2×10⁹ ohms/sq. The vanadium pentoxide coating which had not been provided with an overcoat forming a protective cladding layer had a measured conductivity of greater than 5×10¹² ohms/sq after an equivalent treatment in 0.05M NaOH. The protective cladding layer could also be formed by exposure of the vanadium layer to aniline vapor or by being dipped in neat aniline as shown below in Table 1. The protective cladding layer could also be formed by exposure of the vanadium pentoxide layer to an aqueous solution of pyrrole, to pyrrole vapor, to neat pyrrole, to an alcoholic solution of thiophene, to thiophene vapor or to neat thiophene as shown below in Table 1. All of the final antistatic coatings were colorless.

                  TABLE 1                                                          ______________________________________                                              Ohms/   Ohms/sq    Treatment                                                                             Ohms/sq                                                                               Ohms/sq of                                    sq of   of V.sub.2 O.sub.5                                                                        given to                                                                              of V.sub.2 O.sub.5                                                                    treated V.sub.2 O.sub.5                       V.sub.2 O.sub.5                                                                        layer after                                                                               V.sub.2 O.sub.5                                                                       layer after                                                                           layer after                              Ex 1 layer   0.05M NaOH layer  treatment                                                                             0.05M NaOH                               ______________________________________                                         1    1 × 10.sup.7                                                                     >5 × 10.sup.12                                                                      aniline                                                                               1 × 10.sup.6                                                                    2 × 10.sup.9                                               coating                                                2    1 × 10.sup.7                                                                     >5 × 10.sup.12                                                                      aniline       1 × 10.sup.8                                               vapor                                                  3    1 × 10.sup.7                                                                     >5 × 10.sup.12                                                                      neat          2 × 10.sup.9                                               aniline                                                4    1 × 10.sup.7                                                                     >5 × 10.sup.12                                                                      pyrrole                                                                               1 × 10.sup.6                                                                    2 × 10.sup.7                                               coating                                                5    1 × 10.sup.7                                                                     >5 × 10.sup.12                                                                      pyrrole       2 × 10.sup.8                                               vapor                                                  6    1 × 10.sup.7                                                                     >5 × 10.sup.12                                                                      neat          .sup. 3 × 10.sup.10                                        pyrrole                                                7    1 × 10.sup.7                                                                     >5 × 10.sup.12                                                                      thiophene                                                                             2 × 10.sup.7                                                                    3 × 10.sup.7                                               coating                                                8    1 × 10.sup.7                                                                     >5 × 10.sup.12                                                                      thiophene     7 × 10.sup.8                                               vapor                                                  9    1 × 10.sup.7                                                                     >5 × 10.sup.12                                                                      neat          8 × 10.sup.7                                               thiophene                                              ______________________________________                                    

EXAMPLE 10 A-G Machine coatings of silver-doped vanadium pentoxide of varying vanadium coverages

Aqueous antistatic formulations comprising 0.023 to 0.23 percent silver-doped vanadium pentoxide and 0.02 percent of a nonionic surfactant were machine coated onto a polyethylene terphthalate film support which had been subbed with a terpolymer latex of acylonitrile, vinylidene chloride and acrylic acid. The measured vanadium coverages by Inductively Coupled Argon Plasma/Optical Emission Spectroscopy (ICP/OES) are given in Table 2. Each coating was exposed to 0.05M NaOH for 5 or for 15 seconds and the conductivities and vanadium coverages were measured. These results are given in Table 2.

                                      TABLE 2                                      __________________________________________________________________________               V.sub.2 O.sub.5 V.sub.2 O.sub.5 Coverage                                                                         V.sub.2 O.sub.5 Coverage                     Coverage by ICP/OES                                                                            after 5 sec 0.05M                                                                       OHMS/sq after                                                                           after 15 sec                                                                            OHMS/sq after 15          Example No.                                                                              (mg V.sub.2 O.sub.5 /ft.sup.2)                                                           OHMS/sq                                                                              NaOH (mg/ft.sup.2)                                                                      5 sec 0.05M NaOH                                                                        NaOH (mg/ft.sup.2)                                                                      sec 0.05M                 __________________________________________________________________________                                                          NaOH                      10A       0.222     5.33 × 10.sup.9                                                                0.058    5.00 × 10.sup.12                                                                  0.056    9 × 10.sup.11       10B       0.464     5.67 × 10.sup.8                                                                0.069    5.00 × 10.sup.12                                                                  0.04     5 × 10.sup.12       10C       1.02      4.97 × 10.sup.7                                                                0.031    5.00 × 10.sup.12                                                                  0.044    1 × 10.sup.12       10D       0.92      6.97 × 10.sup.7                                                                0.06     5.00 × 10.sup.12                                                                  0.051    5 × 10.sup.12       10E       1.34      3.10 × 10.sup.7                                                                0.049    5.00 × 10.sup.12                                                                  0.056    5 × 10.sup.12       10F       1.45      3.12 × 10.sup.7                                                                0.049    5.00 × 10.sup.12                                                                  0.038    5 × 10.sup.12       10G       3.43      2.00 × 10.sup.7                                                                0.18     2.00 × 10.sup.8                                                                   0.056    2 × 10.sup.12       (Hand Coating 0.57%)                                                           __________________________________________________________________________

EXAMPLE 11 Preparation of Base Resistant Antistat Layers from machine coatings of silver doped vanadium pentoxide of varying vanadium coverage and monomer overcoats

The V₂ O₅ films described in Example 10 were conditioned at 100% RH. An aqueous formulation comprised of 1 percent aniline and 0.02 percent nonionic surfactant was coated onto the films using a doctor blade. The coatings were dried at 90° C. for 5 minutes and a 125° C. for 1 minute to form antistatic layers. The conductivities of these coatings are shown in Table 3. The films described in Example 10 were also coated with solutions of pyrrole or thiophene. These results are also given in Table 3.

If the V₂ O₅ films described in Example 11 were not conditioned at 100% RH and were coated as above, the protective cladding layer was not formed, showing that the coatings of the vanadium oxide must be freshly coated or in a slightly water swollen condition. These results are given in Table 4.

                                      TABLE 3                                      __________________________________________________________________________     Conditioned at 100% RH                                                                                                               OHMS/sq after                              OHMS/sq -overcoat OHMS/sq after     overcoat (1%                     OHMS/sq after                                                                            (1% aniline in                                                                          OHMS/sq after                                                                           overcoat (1%                                                                            OHMS/sq after                                                                           thiophene in EtOH)               overcoat (1% aniline                                                                     water) & 15 sec                                                                         overcoat (1%                                                                            pyrrole in water) &                                                                     overcoat (1%                                                                            & 15 sec 0.05M           Example No.                                                                            in water) 0.05M NaOH                                                                              pyrrole in water)                                                                       15 sec 0.05M NaOH                                                                       thiophene in                                                                            NaOH)                    __________________________________________________________________________     11A     .sup. 5.00 × 10.sup.12                                                             .sup. 5.00 × 10.sup.12                                                            .sup. 5.00 × 10.sup.12                                                            .sup. 5.00 × 10.sup.12                                                            .sup. 5.00                                                                     × 10.sup.12                                                                       .sup. 5.00 ×                                                             10.sup.12                11B     5.70 × 10.sup.8                                                                    .sup. 2.00 × 10.sup.10                                                            6.40 × 10.sup.8                                                                   7.30 × 10.sup.9                                                                   6.70 × 10.sup.8                                                                   7.80 ×                                                                   10.sup.9                 11C     4.90 × 10.sup.7                                                                    7.00 × 10.sup.9                                                                   5.90 × 10.sup.7                                                                   5.10 × 10.sup.9                                                                   5.30 × 10.sup.8                                                                   3.20 ×                                                                   10.sup.9                 11D     8.80 × 10.sup.7                                                                    6.30 × 10.sup.9                                                                   6.60 × 10.sup.7                                                                   9.00 × 10.sup.8                                                                   3.80 × 10.sup.7                                                                   1.20 ×                                                                   10.sup.8                 11E     3.70 × 10.sup.6                                                                    .sup. 2.10 × 10.sup.10                                                            4.20 × 10.sup.6                                                                   4.40 × 10.sup.8                                                                   5.20 × 10.sup.6                                                                   9.70 ×                                                                   10.sup.8                 11F     4.20 × 10.sup.6                                                                    7.40 × 10.sup.8                                                                   4.90 × 10.sup.6                                                                   1.10 × 10.sup.8                                                                   6.20 × 10.sup.6                                                                   1.30 ×                                                                   10.sup.8                 11G     2.00 × 10.sup.6                                                                    4.00 × 10.sup.8                                                                   1.00 × 10.sup.6                                                                   1.00 × 10.sup.7                                                                   2.00 × 10.sup.7                                                                   2.00 ×                                                                   10.sup.7                 (Hand 0.57%)                                                                   __________________________________________________________________________

                                      TABLE 4                                      __________________________________________________________________________     Not Conditioned at 100% RH                                                                                                           OHMS/sq after                              OHMS/sq -overcoat OHMS/sq after     overcoat (1%                     OHMS/sq after                                                                            (1% aniline in                                                                          OHMS/sq after                                                                           overcoat (1%                                                                            OHMS/sq after                                                                           thiophene in EtOH)               overcoat (1% aniline                                                                     water) & 15 sec                                                                         overcoat (1%                                                                            pyrrole in water) &                                                                     overcoat (1%                                                                            & 15 sec 0.05M           Example No.                                                                            in water) 0.05M NaOH                                                                              pyrrole in water)                                                                       15 sec 0.05M NaOH                                                                       thiophene in                                                                            NaOH)                    __________________________________________________________________________     11A     .sup. 5.00 × 10.sup.12                                                             5.00 × 10.sup.12                                                                  .sup. 5.00 × 10.sup.12                                                            5.00 × 10.sup.12                                                                  .sup. 5.00                                                                     × 10.sup.12                                                                       5.00 ×                                                                   10.sup.12                11B     4.50 × 10.sup.8                                                                    5.00 × 10.sup.12                                                                  6.20 × 10.sup.8                                                                   5.00 × 10.sup.12                                                                  7.10 × 10.sup.8                                                                   5.00 ×                                                                   10.sup.12                11C     6.10 × 10.sup.7                                                                    5.00 × 10.sup.12                                                                  5.70 × 10.sup.7                                                                   5.00 × 10.sup.12                                                                  4.60 × 10.sup.8                                                                   5.00 ×                                                                   10.sup.12                11D     9.20 × 10.sup.7                                                                    5.00 × 10.sup.12                                                                  8.40 × 10.sup.7                                                                   5.00 × 10.sup.12                                                                  7.70 × 10.sup.7                                                                   5.00 ×                                                                   10.sup.12                11E     4.00 × 10.sup.6                                                                    5.00 × 10.sup.12                                                                  5.30 × 10.sup.6                                                                   5.00 × 10.sup.12                                                                  7.30 × 10.sup.6                                                                   5.00 ×                                                                   10.sup.12                11F     4.10 × 10.sup.6                                                                    5.00 × 10.sup.12                                                                  5.10 × 10.sup.6                                                                   5.00 × 10.sup.12                                                                  7.50 × 10.sup.6                                                                   5.00 ×                                                                   10.sup.12                11G     3.00 × 10.sup.6                                                                    4.00 × 10.sup.9                                                                   1.00 × 10.sup.6                                                                   2.00 × 10.sup.7                                                                   2.00 × 10.sup.7                                                                   3.00 ×                                                                   10.sup.7                 (Hand 0.57%)                                                                   __________________________________________________________________________

EXAMPLE 12 Preparation of Base Resistant Antistat Layers from machine coatings of silver doped vanadium pentoxide of varying vanadium coverage and monomer vapor

The films described in Example 10 were conditioned at 100% RH and exposed to aniline, pyrrole or thiophene vapor. The coatings were dried at 125° C. for 1 minute to form antistatic layers. The conductivities of these coatings are shown in Table 5.

If the films described in Example 12 were not conditioned at 100% RH and were exposed to aniline, thiophene, or pyrrole vapor as above, the protective cladding layer was not formed, showing that the coatings of the vanadium oxide must be freshly coated or in a slightly water swollen condition. These results are given in Table 6.

                                      TABLE 5                                      __________________________________________________________________________     Conditioned at 100% RH and Exposed to Monomer Vapor                                             OHMS/sq 1 hr      OHMS/sq after 1 hr                                                                               OHMS/sq after 1 hr                OHMS/sq after 1 hr                                                                      aniline vapor & 15                                                                      OHMS/sq after 1 hr                                                                      pyrrole vapor & 15                                                                      OHMS/sq after 1                                                                         thiophene vapor &         Example No.                                                                            aniline vapor                                                                           sec 0.05M NaOH                                                                          pyrrole vapor                                                                           sec 0.05M NaOH                                                                          thiophene vapor                                                                         15 sec 0.05M              __________________________________________________________________________                                                          NaOH                      12A     .sup. 5.00 × 10.sup.12                                                            .sup. 5.00 × 10.sup.12                                                            .sup. 5.00 × 10.sup.12                                                            .sup. 5.00 × 10.sup.12                                                            .sup. 5.00 × 10.sup.12                                                            .sup. 5.00 ×                                                             10.sup.12                 12B     9.80 × 10.sup.9                                                                   .sup. 1.30 × 10.sup.10                                                            .sup. 1.80 × 10.sup.10                                                            .sup. 2.50 × 10.sup.10                                                            .sup. 8.80 × 10.sup.10                                                            .sup. 5.00 ×                                                             10.sup.10                 12C     8.70 × 10.sup.9                                                                   8.70 × 10.sup.9                                                                   5.20 × 10.sup.9                                                                   7.50 × 10.sup.9                                                                   .sup. 3.00 × 10.sup.10                                                            5.30 ×                                                                   10.sup.9                  12D     4.20 × 10.sup.9                                                                   7.20 × 10.sup.9                                                                   8.70 × 10.sup.9                                                                   5.30 × 10.sup.9                                                                   4.70 × 10.sup.9                                                                   4.10 ×                                                                   10.sup.9                  12E     3.10 × 10.sup.9                                                                   8.60 × 10.sup.8                                                                   1.20 × 10.sup.9                                                                   9.00 × 10.sup.8                                                                   3.80 × 10.sup.9                                                                   5.20 ×                                                                   10.sup.8                  12F     5.40 × 10.sup.8                                                                   7.20 × 10.sup.8                                                                   6.80 × 10.sup.8                                                                   6.00 × 10.sup.8                                                                   5.60 × 10.sup.8                                                                   9.00 ×                                                                   10.sup.8                  12G     1.00 × 10.sup.7                                                                   2.40 × 10.sup.8                                                                   1.00 × 10.sup.7                                                                   2.70 × 10.sup.8                                                                   1.00 × 10.sup.7                                                                   7.70 ×                                                                   10.sup.8                  (Hand 0.57%)                                                                   __________________________________________________________________________

                                      TABLE 6                                      __________________________________________________________________________     Not Conditioned to 100% RH                                                                                                           OHMS/sq after 1 hr                         OHMS/sq 1 hr      OHMS/sq after 1 hr                                                                               thiophene vapor &                OHMS/sq after 1 hr                                                                       aniline vapor & 15                                                                      OHMS/sq after 1 hr                                                                      pyrrole vapor & 15                                                                      OHMS/sq after 1                                                                         15 sec 0.05M             Example No.                                                                            aniline vapor                                                                            sec 0.05M NaOH                                                                          pyrrole vapor                                                                           sec 0.05M NaOH                                                                          thiophene vapor                                                                         NaOH                                                                           OHMS/sq after                              OHMS/sq -overcoat OHMS/sq after     overcoat (1%                     OHMS/sq after                                                                            (1% aniline in                                                                          OHMS/sq after                                                                           overcoat (1%                                                                            OHMS/sq after                                                                           thiophene in EtOH)               overcoat (1% aniline                                                                     water) & 15 sec                                                                         overcoat (1%                                                                            pyrrole in water) &                                                                     overcoat (1%                                                                            & 15 sec 0.05M           Example No.                                                                            in water) 0.05M NaOH                                                                              pyrrole in water)                                                                       15 sec 0.05M NaOH                                                                       thiophene in                                                                            NaOH)                    __________________________________________________________________________     12A     .sup. 5.00 × 10.sup.12                                                             5.00 × 10.sup.12                                                                  .sup. 5.00 × 10.sup.12                                                            5.00 × 10.sup.12                                                                   5.00 × 10.sup.12                                                                 5.00 ×                                                                   10.sup.12                12B     .sup. 2.00 × 10.sup.10                                                             5.00 × 10.sup.12                                                                  .sup. 1.10 × 10.sup.10                                                            5.00 × 10.sup.12                                                                  8.90 × 10.sup.9                                                                   5.00 ×                                                                   10.sup.12                12C     8.90 × 10.sup.9                                                                    5.00 × 10.sup.12                                                                  7.80 × 10.sup.9                                                                   5.00 × 10.sup.12                                                                  .sup. 1.00                                                                              5.00 ×                                                                   10.sup.12                12D     5.34 × 10.sup.9                                                                    5.00 × 10.sup.12                                                                  3.30 × 10.sup.9                                                                   5.00 × 10.sup.12                                                                  4.50 × 10.sup.9                                                                   5.00 ×                                                                   10.sup.12                12E     3.30 × 10.sup.9                                                                    5.00 × 10.sup.12                                                                  3.40 × 10.sup.9                                                                   5.00 × 10.sup.12                                                                  3.60 × 10.sup.9                                                                   5.00 ×                                                                   10.sup.12                12F     8.70 × 10.sup.8                                                                    5.00 × 10.sup.12                                                                  7.60 × 10.sup.8                                                                   5.00 × 10.sup.12                                                                  6.50 × 10.sup.8                                                                   5.00 ×                                                                   10.sup.12                12G     1.00 × 10.sup.7                                                                    2.40 × 10.sup.8                                                                   1.00 × 10.sup.7                                                                   2.70 × 10.sup.8                                                                   1.00 × 10.sup.7                                                                   7.70 ×                                                                   10.sup.8                 (Hand 0.57%)                                                                   __________________________________________________________________________

EXAMPLE 13 TEM examination of Base Resistant Antistat Layers made with aniline monomer

A sample of 50 microliters of a 0.57 percent solution of silver-doped vanadium pentoxide was diluted into 10 milliliters of ultrapure water. A four microliter drop of this solution was placed on a copper grid which had been coated with a holey carbon film and air dried for 5 minutes and then in a 125° C. oven for 1 minute. The TEM of this sample showed the fibrous nature of the antistat layer. Micrographs taken of this sample on the holey carbon grid after exposure of the sample to 30 sec in 0.05M NaOH showed that this immersion in base was sufficient to remove all of the fibrous silver-doped vanadium pentoxide in the antistat layer.

Samples of silver-doped vanadium pentoxide prepared above on a holey carbon film were treated with a two microliter drop of a 1 weight percent solution of aniline in water, air dried and then oven dried for 1 minute.

The aniline-treated sample prepared above was then immersed for 30 seconds in 0.05M NaOH, air dried and then oven dried for 1 min. The TEM of this sample shows that some of the fibrous silver-doped vanadium pentoxide layer still remains due to the protective cladding layer formed by interaction of the aniline monomer with the antistat layer.

EXAMPLE 14 TEM examination of Base Resistant Antistat Layers made with thiophene monomer

A sample of 50 microliters of a 0.57 percent solution of silver-doped vanadium pentoxide was diluted into 10 milliliters of ultrapure water. A four microliter drop of this solution was placed on a copper grid which had been coated with a holey carbon film and air dried for 5 minutes and then in a 125° C. oven for 1 minute. The TEM of this sample showed the fibrous nature of the antistat layer. Micrographs taken of this sample on the holey carbon grid after exposure of the sample 30 seconds in 0.05M NaOH shows that this immersion in base was sufficient to remove all of the fibrous silver-doped vanadium pentoxide in the antistat layer.

Samples of silver-doped vanadium pentoxide prepared above on a holey carbon film were treated with a two microliter drop of a 1 weight percent solution of thiophene in ethanol, air dried and then oven dried for 1 minute.

The thiophene-treated sample prepared above was then immersed for 30 seconds in 0.05M NaOH, air dried and then oven dried for 1 minute. The TEM of this sample shows that some of the fibrous silver-doped vanadium pentoxide layer still remains due to the protective cladding layer formed by interaction of the thiophene monomer with the antistat layer.

EXAMPLE 15 TEM examination of Base Resistant Antistat Layers made with pyrrole monomer

A sample of 50 microliters of a 0.57 weight percent solution of silver-doped vanadium pentoxide was diluted into 10 milliliters of ultrapure water. A four microliter drop of this solution was placed on a copper grid which had been coated with a holey carbon film and air dried for 5 minutes and then in a 125° C. oven for 1 minute. The TEM of this sample showed the fibrous nature of the antistat layer. Micrographs taken of this sample on the holey carbon grid after exposure of the sample to 30 seconds in 0.05M NaOH showed that this immersion in base was sufficient to remove all of the fibrous silver-doped vanadium pentoxide in the antistat layer.

Samples of silver-doped vandium pentoxide prepared above on a holey carbon film were treated with a two microliter drop of a 1 weight percent solution of pyrrole in water, air dried and then oven dried for 1 minute.

The pyrrole-treated sample prepared above was then immersed for 30 seconds in 0.05M NaOH, air dried and then oven dried for 1 minute. The TEM of this sample shows that some of the fibrous silver-doped vanadium pentoxide layer still remains due to the protective cladding layer formed by interaction of the pyrrole monomer with the antistat layer.

EXAMPLE 16 Reaction of aniline with silver-doped vanadium pentoxide under strongly acidic conditions

The films described in Example 10 were conditioned at 100% RH and an aqueous formulation comprised of 1 percent aniline in 1.2M HCl and 0.02 weight percent nonionic surfactant was coated onto the films using a doctor blade. The coatings were dried at 90° C. for 5 minutes and at 125° C. for 1 minute. The loss in conductivity of these coatings after immersion in 0.05M NaOH is shown in Table 7, showing that reaction of the aniline monomer with the silver-doped vanadium pentoxide layer under the highly acidic reaction conditions under which reactions producing polyaniline are commonly run did not result in the formation of a protective cladding layer on the silver-doped vanadium pentoxide fibers. TEM examination of samples under these conditions (samples prepared as in Examples 13, 14 and 15 but reacted with aniline in 1.2M HCl) showed no fibrous silver-doped vanadium pentoxide after immersion in 0.05M NaOH.

The NaOH immersed samples in Table 7 did regain conductivity after immersion in 1.2M HCl, washing and drying, showing that a conductive form of polyaniline could be regenerated after reaction of the aniline monomer with the silver-doped vanadium pentoxide layer under highly acidic conditions. The results are shown in the right hand column of Table 7.

                                      TABLE 7                                      __________________________________________________________________________                                                  OHMS/sq -overcoat                                                                       OHMS/sq after ctgs              V.sub.2 O.sub.5 Coverage                                                                   OHMS/sq                                                                               OHMS/sq after                                                                            OHMS/sq -overcoat                                                                       (1% aniline in                                                                          in previous column              by ICP/OES  after 1.2M HCl                                                                        overcoat (1% aniline                                                                     (1% aniline in 1.2M                                                                     HCl)/water                                                                              dipped in 1.2M           Example No.                                                                           (mg V.sub.2 O.sub.5 /ft.sup.2)                                                        OHMS/sq                                                                             overcoat                                                                              in 1.2M HCl)                                                                             Cl) and water wash                                                                      0.5M NaOH                                                                               HCl/wash/dry             __________________________________________________________________________     16A    0.222  5.33 × 10.sup.9                                                               5.00 × 10.sup.12                                                                .sup. 5.00 × 10.sup.12                                                             .sup. 5.00 × 10.sup.12                                                            5.00 × 10.sup.12                                                                  .sup. 5.00 ×                                                             10.sup.12                16B    0.464  5.67 × 10.sup.8                                                               5.00 × 10.sup.12                                                                4.77 × 10.sup.7                                                                    9.63 × 10.sup.8                                                                   5.00 × 10.sup.12                                                                  7.00 ×                                                                   10.sup.8                 16C    1.02   4.97 × 10.sup.7                                                               5.00 × 10.sup.12                                                                4.33 × 10.sup.6                                                                    6.50 × 10.sup.7                                                                   5.00 × 10.sup.12                                                                  2.00 ×                                                                   10.sup.8                 16D    0.92   6.97 × 10.sup.7                                                               5.00 × 10.sup.12                                                                2.33 × 10.sup.6                                                                    3.07 × 10.sup.8                                                                   5.00 × 10.sup.12                                                                  7.00 ×                                                                   10.sup.8                 16E    1.34   3.10 × 10.sup.7                                                               5.00 × 10.sup.12                                                                1.00 × 10.sup.6                                                                    2.43 × 10.sup.7                                                                   5.00 × 10.sup.12                                                                  .sup. 2.00 ×                                                             10.sup.10                16F    1.45   3.12 × 10.sup.7                                                               5.00 × 10.sup.12                                                                1.00 × 10.sup.6                                                                    8.30 × 10.sup.6                                                                   5.00 × 10.sup.12                                                                  .sup. 1.00 ×                                                             10.sup.10                16G    3.43   2.00 × 10.sup.7                                                               1.10 × 10.sup.9                                                                 2.00 × 10.sup.6                                                                    6.00 × 10.sup.6                                                                   5.00 × 10.sup.12                                                                  2.00 ×                                                                   10.sup.8                 (Hand 0.57%)                                                                   __________________________________________________________________________

EXAMPLE 17 Preparation of Base Resistant Antistat Layers

A series of vanadium pentoxide gels containing a variety of different dopants were used to make antistat layers. These alternately doped gels are listed in Table 8.

                                      TABLE 8                                      __________________________________________________________________________           OHMS/sq                                                                              OHMS/sq                                                                  (.057%/3 mil                                                                         (after 1 min                      %                                Example No.                                                                          wet)  base) V4+                                                                               Ag                                                                               LiF                                                                               CaO                                                                               ZnO                                                                               SiO2                                                                              LiCO3                                                                              B2O3                                                                              LiB4O7                                                                             solids                           __________________________________________________________________________     17A    8.1 × 10.sup.7                                                                5.0 × 10.sup.12                                                                4.85                                                                              9.31                                                                             0.63                   4.73                             17B   3.53 × 10.sup.7                                                                5.0 × 10.sup.12                                                                6.21                                                                              8.93                                                                             0.58                   4.91                             17C   2.67 × 10.sup.7                                                                5.0 × 10.sup.12                                                                7.22                                                                              8.27                                                                             0.54                   2.7                              17D   5.40 × 10.sup.7                                                                5.0 × 10.sup.12                                                                4.85                                                                              7.94                                                                             0.61                   4.87                             17E   7.87 × 10.sup.7                                                                5.0 × 10.sup.12                                                                3.23                        4.9                              17F   1.46 × 10.sup.8                                                                5.0 × 10.sup.12                                                                4.8                         4.76                             17G   3.37 × 10.sup.8                                                                5.0 × 10.sup.12                                                                6.93                        4.71                             17H   6.17 × 10.sup.7                                                                5.0 × 10.sup.12                                                                11.08                       4.71                             17I   1.20 × 10.sup.9                                                                5.0 × 10.sup.12                                                                1.67                        3.66                             17J   3.44 × 10.sup.9                                                                5.0 × 10.sup.12                                                                0.91                        3.65                             17K   2.09 × 10.sup.8                                                                5.0 × 10.sup.12                                                                3.44                        3.98                             17L   8.27 × 10.sup.7                                                                5.0 × 10.sup.12                                                                5.17    2                   4.4                              17M   1.54 × 10.sup.8                                                                5.0 × 10.sup.12                                                                5.34    3                   4.16                             17N   1.07 × 10.sup.8                                                                5.0 × 10.sup.12                                                                4.8        2                4.39                             17O   7.13 × 10.sup.7                                                                5.0 × 10.sup.12                                                                4.89       3                4.3                              17P   2.30 × 10.sup.7                                                                5.0 × 10.sup.12                                                                5.03                                                                              4          4             4.29                             17Q   1.50 × 10.sup.7                                                                5.0 × 10.sup.12                                                                4.87                                                                              4          8             4.07                             17R   2.60 × 10.sup.7                                                                5.0 × 10.sup.12                                                                5.28                                                                              4          4             4.26                             17S   3.40 × 10.sup.7                                                                5.0 × 10.sup.12                                                                5.45                                                                              4             4          4.39                             17T   7.00 × 10.sup.6                                                                5.0 × 10.sup.12                                                                5.53                                                                              4             4          2.49                             17U   3.51 × 10.sup.8                                                                5.0 × 10.sup.12                                                                6.02                                                                              4             8          4.43                             17V   1.07 × 10.sup.9                                                                5.0 × 10.sup.12                                                                4.44          4             3.78                             17W   2.14 × 10.sup.9                                                                5.0 × 10.sup.12                                                                4.07          8             4.29                             17X   2.06 × 10.sup.9                                                                5.0 × 10.sup.12                                                                4.28          4             4.13                             17Y   1.44 × 10.sup.9                                                                5.0 × 10.sup.12                                                                4.3           8             3.76                             17Z   4.70 × 10.sup.9                                                                5.0 × 10.sup.12                                                                4.54                 4      4.28                              17A1 9.20 × 10.sup.7                                                                5.0 × 10.sup.12                                                                4.71                                                                              4                 4      4.32                              17B1 2.14 × 10.sup.9                                                                5.0 × 10.sup.12                                                                4.49                    4   4.15                              17C1 3.60 × 10.sup.7                                                                5.0 × 10.sup.12                                                                4.55                                                                              4                    4   4.32                             __________________________________________________________________________

An aqueous antistatic formulation comprised of 0.057 percent of the doped vanadium pentoxide of Table 8 and 0.02 weight percent of a nonionic surfactant was coated with a doctor blade onto a polyethylene terephthalate film support which had been subbed with a terpolymer latex of acrylonitrile, vinylidene chloride and acrylic acid. The coatings were air dried at 90° C. to form antistatic layers with dry weights of approximately 4 milligrams per square foot. An aqueous formulation comprised of 1 percent aniline and 0.02 percent nonionic surfactant was coated onto these films using a doctor blade. The coatings were dried at 90° C. for 5 minutes and at 125° C. for 1 minute to form antistatic layers. These coatings were exposed to 0.05M aqueous NaOH for 1 minute to give antistatic layers with measured conductivities as shown in Table 9. The vanadium pentoxide coatings which had not been provided with an overcoat forming a protective cladding layer had a measured conductivity of greater than 5×10¹² ohms/sq after an equivalent treatment in 0.05M NaOH. All of the final antistatic coatings were colorless.

                  TABLE 9                                                          ______________________________________                                                OHMS/sq  OHMS/sq            OHMS/sq                                     Example                                                                               (.057%/3 (after 1  OHMS/sq  (aniline + 1 min                            No.    mil wet) min base) (after aniline)                                                                         0.05M NaOH)                                 ______________________________________                                         17A    8.10 × 10.sup.7                                                                   5.00 × 10.sup.12                                                                   4.00 × 10.sup.7                                                                   6.90 × 10.sup.9                       17B    3.53 × 10.sup.7                                                                   5.00 × 10.sup.12                                                                   1.80 × 10.sup.7                                                                   4.10 × 10.sup.9                       17C    2.67 × 10.sup.7                                                                   5.00 × 10.sup.12                                                                   3.00 × 10.sup.6                                                                   3.80 × 10.sup.9                       17D    5.40 × 10.sup.7                                                                   5.00 × 10.sup.12                                                                   4.80 × 10.sup.7                                                                   .sup. 1.90 × 10.sup.10                17E    7.87 × 10.sup.7                                                                   5.00 × 10.sup.12                                                                   9.00 × 10.sup.6                                                                   3.00 × 10.sup.6                       17F    1.46 × 10.sup.8                                                                   5.00 × 10.sup.12                                                                   4.00 × 10.sup.8                                                                   9.90 × 10.sup.7                       17G    3.37 × 10.sup.8                                                                   5.00 × 10.sup.12                                                                   1.00 × 10.sup.8                                                                   4.20 × 10.sup.8                       17H    6.17 × 10.sup.7                                                                   5.00 × 10.sup.12                                                                   4.40 × 10.sup.7                                                                   3.20 × 10.sup.9                       17I    1.20 × 10.sup.9                                                                   5.00 × 10.sup.12                                                                   2.30 × 10.sup.8                                                                   2.60 × 10.sup.8                       17J    3.44 × 10.sup.9                                                                   5.00 × 10.sup.12                                                                   5.60 × 10.sup.8                                                                   3.10 × 10.sup.9                       17K    2.09 × 10.sup.8                                                                   5.00 × 10.sup.12                                                                   3.40 × 10.sup.7                                                                   4.70 × 10.sup.8                       17L    8.27 × 10.sup.7                                                                   5.00 × 10.sup.12                                                                   4.90 × 10.sup.7                                                                   5.00 × 10.sup.9                       17M    1.54 × 10.sup.8                                                                   5.00 × 10.sup.12                                                                   5.20 × 10.sup.7                                                                   5.40 × 10.sup.9                       17N    1.07 × 10.sup.8                                                                   5.00 × 10.sup.12                                                                   3.60 × 10.sup.7                                                                   4.10 × 10.sup.9                       17O    7.13 × 10.sup.7                                                                   5.00 × 10.sup.12                                                                   6.10 × 10.sup.7                                                                   9.20 × 10.sup.8                       17P    2.30 × 10.sup.7                                                                   5.00 × 10.sup.12                                                                   1.80 × 10.sup.7                                                                   1.20 × 10.sup.9                       17Q    1.50 × 10.sup.7                                                                   5.00 × 10.sup.12                                                                   4.20 × 10.sup.7                                                                   3.30 × 10.sup.9                       17R    2.60 × 10.sup.7                                                                   5.00 × 10.sup.12                                                                   6.80 × 10.sup.6                                                                   6.70 × 10.sup.8                       17S    3.40 × 10.sup.7                                                                   5.00 × 10.sup.12                                                                   9.20 × 10.sup.6                                                                   2.10 × 10.sup.9                       17T    7.00 × 10.sup.6                                                                   5.00 × 10.sup.12                                                                   2.00 × 10.sup.6                                                                   3.80 × 10.sup.9                       17U    3.51 × 10.sup.8                                                                   5.00 × 10.sup.12                                                                   1.70 × 10.sup.8                                                                   4.40 × 10.sup.9                       17V    1.07 × 10.sup.9                                                                   5.00 × 10.sup.12                                                                   2.40 × 10.sup.8                                                                   3.10 × 10.sup.9                       17W    2.14 × 10.sup.9                                                                   5.00 × 10.sup.12                                                                   2.40 × 10.sup.8                                                                   4.70 × 10.sup.9                       17X    2.06 × 10.sup.9                                                                   5.00 × 10.sup.12                                                                   2.70 × 10.sup.8                                                                   1.20 × 10.sup.9                       17Y    1.44 × 10.sup.9                                                                   5.00 × 10.sup.12                                                                   3.80 × 10.sup.8                                                                   5.50 × 10.sup.9                       17Z    4.70 × 10.sup.9                                                                   5.00 × 10.sup.12                                                                   4.20 × 10.sup.8                                                                   6.40 × 10.sup.9                        17A1  9.20 × 10.sup.7                                                                   5.00 × 10.sup.12                                                                   9.00 × 10.sup.6                                                                   2.20 × 10.sup.8                        17B1  2.14 × 10.sup.9                                                                   5.00 × 10.sup.12                                                                   4.10 × 10.sup.8                                                                   9.10 × 10.sup.9                        17C1  3.60 × 10.sup.7                                                                   5.00 × 10.sup.12                                                                   2.60 × 10.sup.7                                                                   3.30 × 10.sup.8                       ______________________________________                                    

EXAMPLE 18 Preparation of Base Resistant Antistat Layers using alternately doped vanadium pentoxide gels and pyrrole

A series of vanadium pentoxide gels containing a variety of different dopants were used to make antistat layers. These alternately doped gels are listed in Table 8.

An aqueous antistatic formulation comprised of 0.057 weight percent of a doped vanadium pentoxide and 0.02 weight percent of a nonionic surfactant was coated with a doctor blade onto a polyethylene terephthalate film support which had been subbed with a terpolymer latex of acrylonitrile, vinylidene chloride and acrylic acid. The coatings were air dried at 90° C. to form antistatic layers with dry weights of approximately 4 milligrams per square foot. An aqueous formulation comprised of 1 percent pyrrole and 0.02 percent nonionic surfactant was coated onto these films using a doctor blade. The coatings were dried at 90° C. for 5 minutes and at 125° C. for 1 minute to form antistatic layers. These coatings were exposed to 0.05M aqueous NaOH for 1 minute to give antistatic layers with measured conductivities as shown in Table 10. Vanadium pentoxide coatings which had not been provided with an overcoat forming a protective cladding layer had a measured conductivity of greater than 5×10¹² ohms/sq after an equivalent treatment in 0.05M NaOH. All of the final antistatic coatings were colorless.

                  TABLE 10                                                         ______________________________________                                                 OHMS/sq OHMS/sq            OHMS/sq                                     Example (.057%/3                                                                               (after 1  OHMS/sq  (pyrrole + 1 min                            No.     mil wet)                                                                               min base) (after pyrrole)                                                                         0.05M NaOH)                                 ______________________________________                                         18A     8.10 ×                                                                           5.00 × 10.sup.12                                                                   5.00 × 10.sup.7                                                                   9.90 × 10.sup.9                               10.sup.7                                                               18B     3.53 ×                                                                           5.00 × 10.sup.12                                                                   3.60 × 10.sup.7                                                                   2.50 × 10.sup.9                               10.sup.7                                                               18C     2.67 ×                                                                           5.00 × 10.sup.12                                                                   4.00 × 10.sup.6                                                                   1.70 × 10.sup.9                               10.sup.7                                                               18D     5.40 ×                                                                           5.00 × 10.sup.12                                                                   3.80 × 10.sup.7                                                                   2.10 × 10.sup.9                               10.sup.7                                                               18E     7.87 ×                                                                           5.00 × 10.sup.12                                                                   7.00 × 10.sup.6                                                                   3.20 × 10.sup.7                               10.sup.7                                                               18F     1.46 ×                                                                           5.00 × 10.sup.12                                                                   2.80 × 10.sup.8                                                                   6.10 × 10.sup.7                               10.sup.8                                                               18G     3.37 ×                                                                           5.00 × 10.sup.12                                                                   6.20 × 10.sup.7                                                                   2.10 × 10.sup.8                               10.sup.8                                                               18H     6.17 ×                                                                           5.00 × 10.sup.12                                                                   5.80 × 10.sup.7                                                                   .sup. 1.80 × 10.sup.10                        10.sup.7                                                               18I     1.20 ×                                                                           5.00 × 10.sup.12                                                                   2.50 × 10.sup.8                                                                   3.70 × 10.sup.8                               10.sup.9                                                               18J     3.44 ×                                                                           5.00 × 10.sup.12                                                                   9.90 × 10.sup.8                                                                   4.20 × 10.sup.9                               10.sup.9                                                               18K     2.09 ×                                                                           5.00 × 10.sup.12                                                                   2.20 × 10.sup.7                                                                   5.80 × 10.sup.7                               10.sup.8                                                               18L     8.27 ×                                                                           5.00 × 10.sup.12                                                                   3.60 × 10.sup.7                                                                   3.50 × 10.sup.8                               10.sup.7                                                               18M     1.54 ×                                                                           5.00 × 10.sup.12                                                                   5.10 × 10.sup.7                                                                   4.20 × 10.sup.8                               10.sup.8                                                               18N     1.07 ×                                                                           5.00 × 10.sup.12                                                                   4.80 × 10.sup.7                                                                   8.40 × 10.sup.8                               10.sup.8                                                               18O     7.13 ×                                                                           5.00 × 10.sup.12                                                                   5.40 × 10.sup.7                                                                   3.60 × 10.sup.8                               10.sup.7                                                               18P     2.30 ×                                                                           5.00 × 10.sup.12                                                                   1.90 × 10.sup.7                                                                   6.50 × 10.sup.8                               10.sup.7                                                               18Q     1.50 ×                                                                           5.00 × 10.sup.12                                                                   3.20 × 10.sup.7                                                                   3.30 × 10.sup.8                               10.sup.7                                                               18R     2.60 ×                                                                           5.00 × 10.sup.12                                                                   9.10 × 10.sup.6                                                                   2.80 × 10.sup.8                               10.sup.7                                                               18S     3.40 ×                                                                           5.00 × 10.sup.12                                                                   9.00 × 10.sup.6                                                                   2.20 × 10.sup.9                               10.sup.7                                                               18T     7.00 ×                                                                           5.00 × 10.sup.12                                                                   2.00 × 10.sup.6                                                                   2.80 × 10.sup.9                               10.sup.6                                                               18U     3.51 ×                                                                           5.00 × 10.sup.12                                                                   3.10 × 10.sup.8                                                                   5.00 × 10.sup.9                               10.sup.8                                                               18V     1.07 ×                                                                           5.00 × 10.sup.12                                                                   1.70 × 10.sup.8                                                                   .sup. 1.80 × 10.sup.10                        10.sup.9                                                               18W     2.14 ×                                                                           5.00 × 10.sup.12                                                                   4.20 × 10.sup.8                                                                   4.70 × 10.sup.9                               10.sup.9                                                               18X     2.06 ×                                                                           5.00 × 10.sup.12                                                                   2.70 × 10.sup.8                                                                   2.20 × 10.sup.9                               10.sup.9                                                               18Y     1.44 ×                                                                           5.00 × 10.sup.12                                                                   2.70 × 10.sup.8                                                                   9.60 × 10.sup.8                               10.sup.9                                                               18Z     4.70 ×                                                                           5.00 × 10.sup.12                                                                   3.40 × 10.sup.8                                                                   2.30 × 10.sup.9                               10.sup.9                                                                18A1   9.20 ×                                                                           5.00 × 10.sup.12                                                                   8.10 × 10.sup.6                                                                   3.20 × 10.sup.9                               10.sup.7                                                                18B1   2.14 ×                                                                           5.00 × 10.sup.12                                                                   2.30 × 10.sup.8                                                                   4.70 × 10.sup.9                               10.sup.9                                                                18C1   3.60 ×                                                                           5.00 × 10.sup.12                                                                   5.60 × 10.sup.7                                                                   4.20 × 10.sup.9                               10.sup.7                                                               ______________________________________                                    

EXAMPLE 19 Preparation of Base Resistant Antistat Layers using alternately doped vanadium pentoxide gels and thiophene

A series of vanadium pentoxide gels containing a variety of different dopants were used to make antistat layers. These alternately doped gels are listed in Table 8.

An aqueous antistatic formulation comprised of 0.057 percent of a doped vanadium pentoxide and 0.02 percent of a nonionic surfactant was coated with a doctor blade onto a polyethylene terephthalate film support which had been subbed with a terpolymer latex of acrylonitrile, vinylidene chloride and acrylic acid. The coatings were air dried at 90° C. to form antistatic layers with dry weights of approximately 4 milligrams per square foot. An alcoholic formulation comprised of 1 weight percent thiophene was coated onto these films using a doctor blade. The coatings were dried at 90° C. for 5 minutes and at 125° C. for 1 minute to form antistatic layers. These coatings were exposed to 0.05M aqueous NaOH for 1 minute to give antistatic layers with measured conductivities as shown in Table 11. The vanadium pentoxide coatings which had not been provided with an overcoat forming a protective cladding layer had a measured conductivity of greater than 5×10¹² ohms/sq after an equivalent treatment in 0.05M NaOH. All of the final antistatic coatings were colorless.

                  TABLE 11                                                         ______________________________________                                                 OHMS/sq  OHMS/sq   OHMS/sq                                                                               OHMS/sq                                              (.057%/3 (after 1  (after (thiophene + 1 min                           Example No.                                                                            mil wet) min base) thiophene)                                                                            0.05M NaOH)                                  ______________________________________                                         19A     8.10 × 10.sup.7                                                                   5.00 × 10.sup.12                                                                   5.00 × 10.sup.7                                                                 8.00 × 10.sup.9                        19B     3.53 × 10.sup.7                                                                   5.00 × 10.sup.12                                                                   1.60 × 10.sup.7                                                                 5.20 × 10.sup.9                        19C     2.67 × 10.sup.7                                                                   5.00 × 10.sup.12                                                                   7.00 × 10.sup.6                                                                 3.00 × 10.sup.9                        19D     5.40 × 10.sup.7                                                                   5.00 × 10.sup.12                                                                   6.00 × 10.sup.7                                                                 .sup. 1.20 × 10.sup.10                 19E     7.87 × 10.sup.7                                                                   5.00 × 10.sup.12                                                                   8.00 × 10.sup.6                                                                 6.00 × 10.sup.6                        19F     1.46 × 10.sup.8                                                                   5.00 × 10.sup.12                                                                   2.00 × 10.sup.8                                                                 9.10 × 10.sup.7                        19G     3.37 × 10.sup.8                                                                   5.00 × 10.sup.12                                                                   9.20 × 10.sup.7                                                                 1.20 × 10.sup.8                        19H     6.17 × 10.sup.7                                                                   5.00 × 10.sup.12                                                                   4.20 × 10.sup.7                                                                 .sup. 1.20 × 10.sup.10                 19I     1.20 × 10.sup.7                                                                   5.00 × 10.sup.12                                                                   1.90 × 10.sup.8                                                                 3.80 × 10.sup.8                        19J     3.44 × 10.sup.9                                                                   5.00 × 10.sup.12                                                                   6.60 × 10.sup.8                                                                 .sup. 2.90 × 10.sup.10                 19K     2.09 × 10.sup.8                                                                   5.00 × 10.sup.12                                                                   1.40 × 10.sup.7                                                                 4.00 × 10.sup.6                        19L     8.27 × 10.sup.7                                                                   5.00 × 10.sup.12                                                                   9.30 × 10.sup.7                                                                 3.70 × 10.sup.8                        19M     1.54 × 10.sup.8                                                                   5.00 × 10.sup.12                                                                   7.10 × 10.sup.7                                                                 1.20 × 10.sup.9                        19N     1.07 × 10.sup.8                                                                   5.00 × 10.sup.12                                                                   6.40 × 10.sup.7                                                                 1.10 × 10.sup.9                        19O     7.13 × 10.sup.7                                                                   5.00 × 10.sup.12                                                                   4.00 × 10.sup.7                                                                 9.70 × 10.sup.8                        19P     2.30 × 10.sup.7                                                                   5.00 × 10.sup.12                                                                   1.10 × 10.sup.7                                                                 5.50 × 10.sup.9                        19Q     1.50 × 10.sup.7                                                                   5.00 × 10.sup.12                                                                   3.40 × 10.sup.7                                                                 3.20 × 10.sup.9                        19R     2.60 × 10.sup.7                                                                   5.00 × 10.sup.12                                                                   6.00 × 10.sup.6                                                                 8.00 × 10.sup.8                        19S     3.40 × 10.sup.7                                                                   5.00 × 10.sup.12                                                                   7.00 × 10.sup.6                                                                 2.80 × 10.sup.9                        19T     7.00 × 10.sup.6                                                                   5.00 × 10.sup.12                                                                   2.00 × 10.sup.6                                                                 2.80 × 10.sup.9                        19U     3.51 × 10.sup.8                                                                   5.00 × 10.sup.12                                                                   1.10 × 10.sup.8                                                                 5.60 × 10.sup.9                        19V     1.07 × 10.sup.9                                                                   5.00 × 10.sup.12                                                                   1.40 × 10.sup.8                                                                 5.00 × 10.sup.9                        19W     2.14 × 10.sup.9                                                                   5.00 × 10.sup.12                                                                   2.20 × 10.sup.8                                                                 1.70 × 10.sup.9                        19X     2.06 × 10.sup.9                                                                   5.00 × 10.sup.12                                                                   2.30 × 10.sup.8                                                                 2.00 × 10.sup.9                        19Y     1.44 × 10.sup.9                                                                   5.00 × 10.sup.12                                                                   1.80 × 10.sup.8                                                                 4.40 × 10.sup.9                        19Z     4.70 × 10.sup.9                                                                   5.00 × 10.sup.12                                                                   4.20 × 10.sup.8                                                                 8.60 × 10.sup.9                         19A1   9.20 × 10.sup.7                                                                   5.00 × 10.sup.12                                                                   8.50 × 10.sup.6                                                                 4.10 × 10.sup.9                         19B1   2.14 × 10.sup.9                                                                   5.00 × 10.sup.12                                                                   2.10 × 10.sup.8                                                                 8.80 × 10.sup.9                         19C1   3.60 × 10.sup.7                                                                   5.00 × 10.sup.12                                                                   1.60 × 10.sup.7                                                                 9.40 × 10.sup.8                        ______________________________________                                    

EXAMPLE 20 Reaction of aniline with alternately-doped pentoxide under strongly acidic conditions

The films of alternately doped vanadium pentoxides described in Examples 17-19 (Table 8) were coated with an aqueous formulation comprised of 1 weight percent aniline in 1.2M HCl and 0.02 weight percent nonionic surfactant using a doctor blade. The coatings were dried at 90° C. for 5 minutes and at 125° C. for 1 minute. The loss in conductivity of these coatings after immersion in 0.05M NaOH is shown in Table 12, showing that reaction of the an inline monomer with the doped vanadium pentoxide layer under the highly acidic reaction conditions under which reactions producing polyaniline are commonly run did not result in the formation of a protective cladding layer on the doped vanadium pentoxide fibers.

                                      TABLE 12                                     __________________________________________________________________________                              OHMS/sq after                                                                         OHMS/sq after                                                    OHMS/sq after                                                                         overcoat (1%                                                                          aniline/                                             OHMS/sq                                                                              OHMS/sq                                                                              overcoat (1%                                                                          aniline in                                                                            HCl overcoat                                         (0.57%/3 mil                                                                         (after 1 min                                                                         aniline in                                                                            1.2M HCl) &                                                                           and 1 min in                                   Example No.                                                                          wet)  base) 1.2M HCl)                                                                             water wash                                                                            0.05M NaOH                                     __________________________________________________________________________     20A   8.10 × 10.sup.7                                                                5.00 × 10.sup.12                                                               1.00 × 10.sup.6                                                                 1.50 × 10.sup.6                                                                 5.00 × 10.sup.12                         20B   3.53 × 10.sup.7                                                                5.00 × 10.sup.12                                                               1.00 × 10.sup.6                                                                 1.00 × 10.sup.6                                                                 5.00 × 10.sup.12                         20C   2.67 × 10.sup.7                                                                5.00 × 10.sup.12                                                               1.00 × 10.sup.6                                                                 6.50 × 10.sup.6                                                                 5.00 × 10.sup.12                         20D   5.40 × 10.sup.7                                                                5.00 × 10.sup.12                                                               1.00 × 10.sup.6                                                                 2.00 × 10.sup.6                                                                 5.00 × 10.sup.12                         20E   7.87 × 10.sup.7                                                                5.00 × 10.sup.12                                                               1.00 × 10.sup.6                                                                 1.50 × 10.sup.6                                                                 5.00 × 10.sup.12                         20F   1.46 × 10.sup.8                                                                5.00 × 10.sup.12                                                               1.00 × 10.sup.6                                                                 4.00 × 10.sup.6                                                                 5.00 × 10.sup.12                         20G   3.37 × 10.sup.8                                                                5.00 × 10.sup.12                                                               2.00 × 10.sup.6                                                                 7.00 × 10.sup.6                                                                 5.00 × 10.sup.12                         20H   6.17 × 10.sup.7                                                                5.00 × 10.sup.12                                                               4.50 × 10.sup.6                                                                 4.20 × 10.sup.7                                                                 5.00 × 10.sup.12                         20I   1.20 × 10.sup.9                                                                5.00 × 10.sup.12                                                               6.00 × 10.sup.6                                                                 4.80 × 10.sup.7                                                                 5.00 × 10.sup.12                         20J   3.44 × 10.sup.9                                                                5.00 × 10.sup.12                                                               2.50 × 10.sup.6                                                                 4.20 × 10.sup.7                                                                 5.00 × 10.sup.12                         20K   2.09 × 10.sup.8                                                                5.00 × 10.sup.12                                                               1.50 × 10.sup.6                                                                 3.50 × 10.sup.6                                                                 5.00 × 10.sup.12                         20L   8.27 × 10.sup.7                                                                5.00 × 10.sup.12                                                               1.00 × 10.sup.6                                                                 4.00 × 10.sup.6                                                                 5.00 × 10.sup.12                         20M   1.54 × 10.sup.8                                                                5.00 × 10.sup.12                                                               1.00 × 10.sup.6                                                                 1.50 × 10.sup.7                                                                 5.00 × 10.sup.12                         20N   1.07 × 10.sup.8                                                                5.00 × 10.sup.12                                                               1.00 × 10.sup.6                                                                 1.60 × 10.sup.7                                                                 5.00 × 10.sup.12                         20O   7.13 × 10.sup.7                                                                5.00 × 10.sup.12                                                               1.00 × 10.sup.6                                                                 1.20 × 10.sup.7                                                                 5.00 × 10.sup.12                         20P   2.30 × 10.sup.7                                                                5.00 × 10.sup.12                                                               1.00 × 10.sup.6                                                                 3.00 × 10.sup.6                                                                 5.00 × 10.sup.12                         20Q   1.50 × 10.sup.7                                                                5.00 × 10.sup.12                                                               1.00 × 10.sup.6                                                                 2.00 × 10.sup.6                                                                 5.00 × 10.sup.12                         20R   2.60 × 10.sup.7                                                                5.00 × 10.sup.12                                                               1.00 × 10.sup.6                                                                 7.20 × 10.sup.6                                                                 5.00 × 10.sup.12                         20S   3.40 × 10.sup.7                                                                5.00 × 10.sup.12                                                               1.00 × 10.sup.6                                                                 4.50 × 10.sup.7                                                                 5.00 × 10.sup.12                         20T   7.00 × 10.sup.6                                                                5.00 × 10.sup.12                                                               1.00 × 10.sup.6                                                                 7.00 × 10.sup.6                                                                 5.00 × 10.sup.12                         20U   3.51 × 10.sup.8                                                                5.00 × 10.sup.12                                                               1.00 × 10.sup.6                                                                 4.00 × 10.sup.6                                                                 5.00 × 10.sup.12                         20V   1.07 × 10.sup.9                                                                5.00 × 10.sup.12                                                               1.00 × 10.sup.6                                                                 1.60 × 10.sup.7                                                                 5.00 × 10.sup.12                         20W   2.14 × 10.sup.9                                                                5.00 × 10.sup.12                                                               1.00 × 10.sup.6                                                                 4.70 × 10.sup.6                                                                 5.00 × 10.sup.12                         20X   2.06 × 10.sup.9                                                                5.00 × 10.sup.12                                                               1.00 × 10.sup.6                                                                 4.00 × 10.sup.6                                                                 5.00 × 10.sup.12                         20Y   1.44 × 10.sup.9                                                                5.00 × 10.sup.12                                                               1.00 × 10.sup.6                                                                 2.00 × 10.sup.6                                                                 5.00 × 10.sup.12                         20Z   4.70 × 10.sup.9                                                                5.00 × 10.sup.12                                                               1.00 × 10.sup.6                                                                 1.60 × 10.sup.7                                                                 5.00 × 10.sup.12                          20A1 9.20 × 10.sup.7                                                                5.00 × 10.sup.12                                                               1.00 × 10.sup.6                                                                 5.30 × 10.sup.6                                                                 5.00 × 10.sup.12                          20B1 2.14 × 10.sup.9                                                                5.00 × 10.sup.12                                                               1.00 × 10.sup.6                                                                 4.00 × 10.sup.6                                                                 5.00 × 10.sup.12                          20C1 3.60 × 10.sup.7                                                                5.00 × 10.sup.12                                                               1.00 × 10.sup.6                                                                 1.60 × 10.sup.7                                                                 5.00 × 10.sup.12                         __________________________________________________________________________ 

I claim:
 1. Fibrous vanadium pentoxide having a cladding of a polymer formed by the oxidation of an oxidatively polymerizable compound, the vanadium pentoxide being doped with silver.
 2. The fibrous vanadium pentoxide of claim 1 wherein the oxidatively polymerizable compound is selected from the group consisting of an aniline compound, a pyrrole compound, a thiophene compound, a furan compound, a tellurophene compound, a selenophene compound and mixtures thereof.
 3. The fibrous vanadium pentoxide of claim 2 wherein the oxidatively polymerizable compound is an aniline compound.
 4. The fibrous vanadium pentoxide of claim 2 wherein the oxidatively polymerizable compound is a pyrrole compound.
 5. The fibrous vanadium pentoxide of claim 2 wherein the oxidatively polymerizable compound is a thiophene compound.
 6. The fibrous vanadium pentoxide of claim 2 wherein the oxidatively polymerizable compound is a furan compound.
 7. The fibrous vanadium pentoxide of claim 2 wherein the oxidatively polymerizable compound is a tellurophene compound.
 8. The fibrous vanadium pentoxide of claim 2 wherein the oxidatively polymerizable compound is a selenophene compound.
 9. An antistat layer comprising vanadium pentoxide fibers clad with a polymer formed by the oxidation of an oxidatively polymerizable compound, the vanadium pentoxide being doped with silver.
 10. The anitstat layer of claim 9 wherein the oxidatively polymerizable compound is selected from the group consisting of an aniline compound, a pyrrole compound, a thiophene compound, a furan compound, a tellurophene compound, a selenophene compound and mixtures thereof.
 11. The antistat layer of claim 10 wherein the oxidatively polymerizable compound is an aniline compound.
 12. The antistat layer of claim 10 wherein the oxidatively polymerizable compound is a pyrrole compound.
 13. The anitstat layer of claim 10 wherein the oxidatively polymerizable compound is a thiophene compound.
 14. The antistat layer of claim 10 wherein the oxidatively polymerizable compound is a furan compound.
 15. The antistat layer of claim 10 wherein the oxidatively polymerizable compound is a tellurophene compound.
 16. The antistat layer of claim 10 wherein the oxidatively polymerizable compound is a selenophene compound. 